Details
Chinese factory supply ZINC PHTHALOCYANINE 14320-04-8 in stock with high standard
- Molecular Formula: C32H16N8Zn
- Molecular Weight: 577.923
- Appearance/Colour: purple powder
- Vapor Pressure: 0.01-1.8Pa at 20-475℃
- PSA： 99.94000
- Density: 1.614-1.62g/cm3 at 20℃
- LogP: 1.14850
ZINC PHTHALOCYANINE(Cas 14320-04-8) Usage
|
Purification Methods |
Sublime it in oxygen-free N2. [Beilstein 26 III/IV 4257.] |
|
General Description |
Zinc phthalocyanine (ZnPc) is a metallophthalocyanine complex where zinc(II) is coordinated by four nitrogen atoms of the phthalocyanine (Pc) ligand, forming a stable planar structure. It exhibits strong π-π stacking interactions, leading to supramolecular assemblies, and demonstrates notable electrochemical properties, including solvent-dependent redox behavior under variable pressure conditions. ZnPc can also be synthesized under mild conditions, such as via room-temperature condensation or metal insertion methods, and is often studied for its optical, structural, and coordination characteristics, including fluorescence and absorption spectroscopy. |
InChI:InChI=1/C32H18N8.Zn/c1-2-10-18-17(9-1)25-33-26(18)38-28-21-13-5-6-14-22(21)30(35-28)40-32-24-16-8-7-15-23(24)31(36-32)39-29-20-12-4-3-11-19(20)27(34-29)37-25;/h1-16H,(H2,33,34,35,36,37,38,39,40);/q;+2
14320-04-8 Relevant articles
The solid phase, room-temperature synthesis of metal-free and metallophthalocyanines, particularly of 2,3,9,10,16,17,23,24-octacyanophthalocyanines
Nemykin, Victor N.,Kobayashi, Nagao,Mytsyk, Vladislav M.,Volkov, Sergey V.
, p. 546 - 547 (2000)
Room-temperature synthesis of phthalocya...
Synthesis and Aggregation Studies of Functional Binaphthyl-Bridged Chiral Phthalocyanines
Revuelta-Maza, Miguel á.,Torres, Tomás,Torre, Gema De La
, p. 8183 - 8186 (2019)
We describe the preparation of a battery...
Novel synthesis of phthalocyanines from phthalonitriles under mild conditions
Uchida, Hitoshi,Tanaka, Hirokazu,Yoshiyama, Hideyuki,Reddy, Paidi Yella,Nakamura, Shuichi,Toru, Takeshi
, p. 1649 - 1652 (2002)
A convenient preparation of phthalocyani...
Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex
Cui, Li-Ying,Yang, Jin,Fu, Qiang,Zhao, Bao-Zhong,Tian, Lei,Yu, Hai-Ling
, p. 149 - 154 (2007)
A new complex [ZnPc(H2O)]·2DMF (1), wher...
Electrochemistry of metal phthalocyanines in organic solvents at variable pressure
Yu, Bazhang,Lever,Swaddle, Thomas W.
, p. 4496 - 4504 (2004)
High-pressure electrochemical investigat...
Electronic energy levels of organic dyes on silicon: A photoelectron spectroscopy study of ZnPc, F16ZnPc, and ZnTPP on p-Si(111):H
Weiler, Ulrich,Mayer, Thomas,Jaegermann, Wolfram,Kelting, Christian,Schlettwein, Derck,Makarov, Sergey,Woì?hrle, Dieter
, p. 19398 - 19403 (2004)
Alignment of energy levels and chemical ...
Zn phthalocyanine/carbon nitride heterojunction for visible light photoelectrocatalytic conversion of CO2 to methanol
Zheng, Jingui,Li, Xiaojie,Qin, Yuhu,Zhang, Shuqin,Sun, Mingsheng,Duan, Xiaoguang,Sun, Hongqi,Li, Peiqiang,Wang, Shaobin
, p. 214 - 223 (2019)
Zinc phthalocyanine/carbon nitride nanos...
Preparation of non-substituted metal phthalocyanines at low temperature using activated Rieke zinc and magnesium
Kharisov,Garza-Rodriguez,Leija Gutierrez,Ortiz Mendez,Garcia Caballero,Tsivadze
, p. 755 - 760 (2005)
Synthesis of non-substituted metal phtha...
Chemically reversible reactions of hydrogen sulfide with metal phthalocyanines
Hartle, Matthew D.,Sommer, Samantha K.,Dietrich, Stephen R.,Pluth, Michael D.
, p. 7800 - 7802 (2014)
Hydrogen sulfide (H2S) is an important s...
Zinc phthalocyanine coupled with UIO-66 (NH2) via a facile condensation process for enhanced visible-light-driven photocatalysis
Liang, Qian,Zhang, Miao,Zhang, Zhihui,Liu, Changhai,Xu, Song,Li, Zhongyu
, p. 123 - 130 (2017)
Metal-organic frameworks (MOFs) have sho...
Phthalocyanization of Cadmium Sulfide and Zinc Oxide. Effects on the Photochemistry in Aqueous Dispersion
Harbour, John R.,Dietelbach, Bonita,Duff, James
, p. 5456 - 5460 (1983)
A novel method for the synthesis of meta...
Photoelectron spectroscopy on thin films of extended zinc porphyrazines
Pop,Winter,Freyer,Widdra,Hertel
, p. 7826 - 7833 (2005)
Photoemission measurements were performe...
Green synthesis and characterization of crystalline zinc phthalocyanine and cobalt phthalocyanine prisms by a simple solvothermal route
Li, Dapeng,Ge, Suxiang,Yuan, Tianci,Gong, Jingjing,Huang, Baojun,Tie, Weiwei,He, Weiwei
, p. 2749 - 2758 (2018)
A facile, environmentally-friendly and l...
Sustainable approaches to the synthesis of metallophthalocyanines in solution
Imperatori, Patrizia,Paoletti, Anna Maria,Pennesi, Giovanna,Zanotti, Gloria
, (2021)
This work aims to investigate more susta...
Coordination properties of diethylenetriamine in relation to zinc phthalocyanine
Janczak, Jan
, (2020)
The coordination properties of diethylen...
Solvent Effects on Crystal Growth and Transformation of Zinc Phthalocyanine
Iwatsu, Fumio,Kobayashi, Takashi,Uyeda, Natsu
, p. 3223 - 3230 (1980)
The process of α --> β crystal transform...
Syntheses and Characterization of Bromo- and Chloro(phthalocyaninato)bismuth(III) Complexes
Isago, Hiroaki,Kagaya, Yutaka
, p. 383 - 389 (1994)
By the reactions of BiX3 (X=Cl-, Br-, I-...
Isomorphic complexes formed by recrystallisation of M(II)Pc (M(II) = Mg, Mn and Zn) in liquid 2-amino-3-picoline
Janczak, Jan,Kubiak, Ryszard,Bukowska, Ewa
, p. 25 - 33 (2009)
Three isomorphic, Mg, Mn and Zn phthaloc...
Comparative study of beryllium, magnesium and zinc phthalocyanine complexes with 4-picoline
Kubiak,Janczak,?led?,Bukowska
, p. 4179 - 4186 (2007)
Three new Be(II), Mg(II) and Zn(II) phth...
Rational design of a reactive yet stable organic-based photocatalyst
Gerdes, Robert,Lapok, Lukasz,Tsaryova, Olga,Woehrle, Dieter,Gorun, Sergiu M.
, p. 1098 - 1100 (2009)
Zinc perfluoro-fluoroalkyl-phthalocyanin...
Fluorinated phthalocyanines as molecular semiconductor thin films
Brinkmann,Kelting,Makarov,Tsaryova,Schnurpfeil,Woehrle,Schlettwein
, p. 409 - 420 (2008)
Thin films of pefluorinated phthalocyani...
Effects of MN4-Type Coordination Structure in Metallophthalocyanine for Bio-Inspired Oxidative Desulfurization Performance
Tan, Amin,Tian, Min,Yang, Yan,Zhang, Gai,Zhang, Yufan
, (2022/02/14)
Oxidative desulfurization (ODS) is the p...
Visible-light-mediated phosphonylation reaction: formation of phosphonates from alkyl/arylhydrazines and trialkylphosphites using zinc phthalocyanine
Hosseini-Sarvari, Mona,Koohgard, Mehdi
, p. 5905 - 5911 (2021/07/12)
In this work, we developed a ligand- and...
Nanostructural catalyst: Metallophthalocyanine and carbon nano-onion with enhanced visible-light photocatalytic activity towards organic pollutants
Brzezinski, Krzysztof,Butsyk, Olena,Chaur, Manuel N.,Czyrko-Horczak, Justyna,Echegoyen, Luis,Olejnik, Piotr,Plonska-Brzezinska, Marta E.,Regulska, Elzbieta,Tomczykowa, Monika,Zubyk, Halyna
, p. 10910 - 10920 (2020/03/30)
Metallophthalocyanine (MPc) and carbon n...
14320-04-8 Process route
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5970-45-6
zinc(II) acetate dihydrate
-
-
91-15-6
phthalonitrile
-
-
14320-04-8
zinc(II) phthalocyanine
| Conditions | Yield |
|---|---|
|
In
N,N-dimethyl-formamide;
at 200 ℃;
for 0.166667h;
Microwaves;
|
95%
|
|
In
N,N-dimethyl-formamide;
other Radiation; to mixt. Zn(OAc)2*2H2O and phthalonitrile DMF was added and heated in microwave Discover CEM reactor to 200°C for 10 min in sealed tube; Soxhlet extraction with acetone, CH2Cl2, and MeCN followed by recrystn. from pyridine;
|
95%
|
|
In
N,N-dimethyl-formamide;
at 110 ℃;
for 0.00694444h;
under 7500.75 Torr;
Pressure;
Microwave irradiation;
|
92%
|
|
With
butyl(2-hydroxyethyl)dimethylammonium acetate;
at 100 ℃;
for 2h;
Ionic liquid;
Inert atmosphere;
|
86%
|
|
With
1,8-diazabicyclo[5.4.0]undec-7-ene;
at 135 ℃;
for 3h;
Reagent/catalyst;
Inert atmosphere;
|
75%
|
-
-
557-34-6
zinc diacetate
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-
91-15-6
phthalonitrile
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-
14320-04-8
zinc(II) phthalocyanine
| Conditions | Yield |
|---|---|
|
With
sodium methylate;
In
tetrahydrofuran;
3 equiv. NaOMe, 20 °C, stirring for 7 days, addn. of metal salt,stirring for 3 days;
|
82%
|
|
With
1,8-diazabicyclo[5.4.0]undec-7-ene;
In
pentan-1-ol;
under N2, 1,8-diazabicyclo(5.4.0)undec-7-ene (5 mmol) added to C6H4(CN)2(5 mmol) and Zn(CH3COO)2 (1.25 mmol) soln., heated for 36 h under reflu x; D. Woehrle, G. Schnurpfel, G. Knothe, Dyes Pigm. 18, 91 (1992); MeOH added, washed (with H2O and MeOH), treated with MeOH in Soxhlet apparatus overnight, dried.; purified by sublimation in vac. at 370°C;
|
75%
|
|
With
1,8-diazabicyclo[5.4.0]undec-7-ene;
In
pentan-1-ol;
for 12h;
Inert atmosphere;
Reflux;
|
48%
|
|
With
1,8-diazabicyclo[5,4,0]undec-7-ene;
In
pentan-1-ol;
reflux; filtration, washing (water), extraxting with MeOH in a Soxhilet apparatus, zone sublimation at 1E-7 - 1E-6 mbar at 370 °C;
|
|
|
In
ethanol;
at 160 ℃;
for 6h;
Solvent;
Autoclave;
High pressure;
Green chemistry;
|
14320-04-8 Upstream products
-
91-15-6
phthalonitrile
-
136918-14-4
phthalimide
-
649553-08-2
3-[4-(hydroxymethyl)phenoxy]phthalonitrile
-
649553-07-1
4-[4-(hydroxymethyl)phenoxy]phthalonitrile
14320-04-8 Downstream products
-
574-93-6
29H,31H-Phthalocyanine
-
574-93-6
29H,31H-phthalocyanine
-
176677-55-7
bis(triphenylphosphine)iminium nitrito(phralocyaninato)zincate hydrate
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